Molten salt applications

Topic

In this field, Fraunhofer IKTS is focusing on the development of materials with improved corrosion stability in molten carbonates and chlorides. In case of ceramic materials, we deal with the synthesis of powder materials, their sintering, preparation and characterization of defined components. The following applications are addressed:

Molten-salt electrolysis in chlorides

  • Investigation of CaRuO3 as an inert-anode candidate material, potential for energy-efficient extraction of metals and oxygen from minerals

Molten-carbonate fuel cells (MCFC)

  • Stabilizing defined phases of LiAlO2 at high temperatures (600-700°C) in molten alkali carbonates under different gas ambience
  • Preparing corrosion protection and anti-adhesion layers for molten carbonates

In-situ electrochemical characterization

  • MCFC materials, CO2 gas sensors, proton conductors

 

Specifications of test equipment

 

Box furnaces

  • Air, N2 (up to 1400°C), reducing gas mixtures (up to 1100°C)


MCFC half-cell test rigs, adaptable for testing other components

  • In-situ electrochemical characterization in defined gas mixture, temperatures up to 675°C
  • Cathode half-cell (oxidizing gas): air, N2, CO2, H2O
  • Anode half cell (reducing gas): H2, N2, CO2, H2O
  • Designed for long-term experiments (>1000 h)
  • Parallel testing of multiple components at different parameters

MCFC single-cell test rig         

  • In-situ electrochemical characterization
  • Temperatures up to 1100°C
  • Tests with variation of gas composition
  • Characterization of complete working molten-carbonate fuel cell
  • Adaptable for simplified electrolysis tests in molten chlorides
  • Designed for long-term experiments (> 1000 h)

Services offered
 

  • Development of materials with improved stability for systems with molten salts
  • Testing corrosion stability of customer-specific materials in molten carbonates and chlorides
  • In-situ electrochemical impedance spectroscopy characterization during the tests (MCFC half cells, button cells, electrochemical gas sensors)

 

Further information